HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cerium(III) chloride → HCID 59273074, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cerium(III) chloride | HCID 24636 | — |
| Reactant | benzyl (2S)-2-isopropyl-3-oxopyrrolidine-1-carboxylate | HCID 59273063 | — |
| Reactant | HCID 178467792 | HCID 178467792 | — |
| Product | HCID 59273074 | HCID 59273074 | — |
Reaction Steps
By an operation in the same manner as in Reference Example 3 and using cerium chloride (9.25 g), 3 mol/L ethylmagnesium bromide-diethyl ether solution (11.0 mL) and benzyl (2S)-2-isopropyl-3-oxopyrrolidine-1-carboxylate (3.92 g), the title compound was obtained as colorless oil (yield: 2.21 g, yield: 51%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08013008B2 |
| Source dataset | uspto-grants-2011_09 |
| ORD ID | ord-c2acd820ffd54eacaa4cb46ff16afa6d |
| Source note | uspto-grants-2011_09 |