huagongshe.com
HRID906964

反应详情

EQUATION

反应方程式

HRID 906964 的结构方程式

REACTANTS

反应物

3
结构：[Ce+3].[Cl-].[Cl-].[Cl-]
HCID24636

Cerium trichloride

CeCl3

结构：CC(C)[C@H]1C(=O)CCN1C(=O)OCc1ccccc1
HCID59273063

未命名化合物

结构：Br[Mg]C1CC1.C1CCOC1
HCID178420628

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)[C@@H]1N(C(=O)OCc2ccccc2)CC[C@@]1(O)C1CC1
HCID59273012

未命名化合物

PROCEDURE

实验过程

By an operation in the same manner as in Reference Example 3 and using cerium chloride (7.40 g), 0.5 mol/L cyclopropylmagnesium bromide—THF solution (52.8 mL) and benzyl (2S)-2-isopropyl-3-oxopyrrolidine-1-carboxylate (3.14 g), the title compound was obtained as colorless oil (yield: 2.31 g, yield: 63%).