HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylpyridine-4-boronic acid → 2-Chloro-5-(2-methyl-4-pyridinyl)phenyl 2,3,4-tri-O-acetyl-5-thio-beta-D-xylopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylpyridine-4-boronic acid | HCID 4192664 | — |
| Reactant | 5-bromo-2-chlorophenyl 2,3,4-tri-O-acetyl-5-thio-beta-D-xylopyranoside | HCID 67395633 | — |
| Product | 2-Chloro-5-(2-methyl-4-pyridinyl)phenyl 2,3,4-tri-O-acetyl-5-thio-beta-D-xylopyranoside | HCID 67396603 | — |
Reaction Steps
By carrying out the operation analogously to example 3, starting from 5-bromo-2-chlorophenyl 2,3,4-tri-O-acetyl-5-thio-β-D-xylopyranoside, obtained according to preparation X, and 2-methyl-4-pyridineboronic acid, the expected product is obtained and is reacted further without additional purification in order to obtain the nonacetylated xyloside.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08013010B2 |
| Source dataset | uspto-grants-2011_09 |
| ORD ID | ord-11394fffa15043b5a738fdf9814aef7c |
| Source note | uspto-grants-2011_09 |