Acetate → 2-(2-Pentynyl)-2-cyclopenten-1-one

HRID 91479Notes

Reaction equation

HRID 91479 reaction equation
[C:18]([O-:19])(=[O:20])[CH3:21].[C:23]([O-:24])(=[O:25])[CH3:26].[CH2:1]([C:2]#[C:3][CH2:4][CH3:5])[C:6]1([C:12]([O:13][CH2:14][CH:15]=[CH2:16])=[O:17])[C:7](=[O:11])[CH2:8][CH2:9][CH2:10]1.[CH3:27][C:28]#[N:29].[Pd+2:22]>>[CH2:1]([C:2]#[C:3][CH2:4][CH3:5])[C:6]1=[CH:10][CH2:9][CH2:8][C:7]1=[O:11]

Participants

5

Reactant 4

HCID 175Acetate2×HCID 6342AcetonitrileHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 10868228Cyclopentanecarboxylic acid, 2-oxo-1-(2-pentynyl)-, 2-propenyl ester

Product 1

HCID 110080722-(2-Pentynyl)-2-cyclopenten-1-one

Sources & evidence

ORD record
ord-920e2e3b4ce74dbd9998e2d5f276c8fb
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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