HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylene carbonate → 2-(Phenylthio)ethanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylene carbonate | HCID 7303 | — |
| Reactant | Thiophenol | HCID 7969 | — |
| Product | 2-(Phenylthio)ethanol | HCID 69685 | — |
Reaction Steps
Benzenethiol is reacted with 1,3-dioxolan-2-one to form 2-(phenylthio)ethanol. The 2-(phenylthio)ethanol is isolated and then converted to 2-(phenylthio)ethanethiol using triphenylphosphine, diisopropyl azodicarboxylate (DIAD), and thiolacetic acid followed by hydrolysis of the resulting acetate with potassium hydoxide in methanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07271283B2 |
| Source dataset | uspto-grants-2007_09 |
| ORD ID | ord-b9fa317545da43eba563c8ceea1dafa7 |
| Source note | uspto-grants-2007_09 |