HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromine → 2-[Bromo(nitro)methylidene]-1-methylimidazolidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 1-Methyl-2-(nitromethylidene)imidazolidine | HCID 70250046 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2-[Bromo(nitro)methylidene]-1-methylimidazolidine | HCID 70638955 | — |
Reaction Steps
A stirred solution of 3.57 grams of 1-methyl-2(nitromethylene)imidazolidine (Compound 1) in 25 milliliters of water was treated dropwise with 3.99 grams of bromine at room temperature. After 30 minutes, the reaction mixture was extracted with methylene chloride. The extract was dried (MgSO4) and the solvent was evaporated to give 3.0 grams of crude product, melting point 100° (with vigorous decomposition). Recrystallization of the crude product from methylene chloride gave 15, melting point: 97° (explodes).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03969354 |
| Source dataset | uspto-grants-1976_07 |
| ORD ID | ord-aba6bbb82a6a497eb5fecfac18c2958d |
| Source note | uspto-grants-1976_07 |