1,3-Diamino-5-methylphenazin-5-ium chloride → HCID 2796919, compound

HRID 918221Notes

Reaction equation

HRID 918221 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:21]=[CH:22][CH:23]=1)[CH:7]=[C:8]1[S:12][C:11](=[S:13])[N:10](C2C=CC=CC=2)[C:9]1=[O:20])([O-:3])=[O:2].C(N1C(=O)C(=CC2C=CC=C([N+]([O-])=O)C=2)SC1=S)C.C(N1C(=O)C(=CC2C=CC([N+]([O-])=O)=CC=2[N+]([O-])=O)SC1=S)C.[N+](C1C=CC=CC=1C=C1SC(=S)N(C2C=CC=CC=2)C1=O)([O-])=O.ClC1C=C([N+]([O-])=O)C2N=NNC=2C=1.CN(C)C1C=CC(N=CC2SC3C=CC=CC=3N=2)=CC=1.[Cl-].NC1C2C(=[N+](C)C3C(N=2)=CC=CC=3)C=C(N)C=1.[I-].S1C2C=CC=CC=2N=C1N1C(C2C=CC=CC=2)=CC(C2C=CC=CC=2)=CC1C=CC1C=CC(N(C)C)=CC=1.[Cl-].C1(N2N(C3C=CC=CC=3)N=C(C3C=CC=CC=3)[NH2+]2)C=CC=CC=1.[Cl-].IC1C=CC(N2N(C3C=CC([N+]([O-])=O)=CC=3)N=C(C3C=CC=CC=3)[NH2+]2)=CC=1.COS([O-])(=O)=O.C[N+]1C2C(=CC=CC=2[N+]([O-])=O)C=CC=1.C(N1C2C=CC=CC=2SC1=CC=CC=C1C(=O)C(=O)C(=CC=CC=C2N(CC)C3C=CC=CC=3S2)C(=O)C1=O)C>>[N+:1]([C:4]1[CH:5]=[C:6]([CH:21]=[CH:22][CH:23]=1)[CH:7]=[C:8]1[S:12][C:11](=[S:13])[NH:10][C:9]1=[O:20])([O-:3])=[O:2]

Participants

13

Reactant 12

HCID 141321,3-Diamino-5-methylphenazin-5-ium chlorideHCID 349368HCID 349368, compoundHCID 12740734-Thiazolidinone, 5-[(3-nitrophenyl)methylene]-3-phenyl-2-thioxo-HCID 1521901HCID 1521901, compoundHCID 2132556752688-57-0HCID 53249492HCID 53249492, compoundHCID 53445262HCID 53445262, compoundHCID 53678376HCID 53678376, compoundHCID 53773635HCID 53773635, compoundHCID 73795156HCID 73795156, compoundHCID 86733711HCID 86733711, compoundHCID 178526655HCID 178526655, compound2×

Product 1

HCID 2796919HCID 2796919, compound

Procedure

5-m-nitrobenzylidene-3-phenylrhodanine; 3-ethyl-5-m-nitrobenzylidenerhodanine; 3-ethyl-5-(2,4-dinitrobenzylidene)rhodanine; 5-o-nitrobenzylidene-3-phenylrhodanine; 6-chloro-4-nitrobenzotriazole; 2-(p-dimethylaminophenyliminomethyl)-benzothiazole ethoethylsulfate; 1,3-diamino-5-methylphenazinium chloride; 4-nitro-6-chlorobenzotriazole; anhydro-2-p-dimethylaminophenyliminomethyl-6-nitro-3-(4-sulfobutyl)benzothiazoline hydroxide; 1-(2-benzothiazolyl)-2-(p-dimethylaminostyryl)-4,6-diphenylpyridine iodide; 1,3-diethyl-5-[1,3-neopentylene-6-(1,3,3-trimethyl-2-indolinylidene)-2,4-hexadienylidene]-2-thiobarbituric acid; 2,3,5-triphenyl-2H-tetrazolium chloride; 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyl-tetrazolium chloride; 1-methyl-8-nitroquinolinium methylsulfate; 3,6-bis[4-(3-ethyl-2-benzothiazolinylidene)-2-butenylidene]-1,2,4,5-cyclohexanetetrone; and the like. The proportion of these electron acceptors added can range from about 100 mg to 2 g per 1 mole of silver halide.

Workup

  1. additionThe proportion of these electron acceptors added can

Sources & evidence

ORD record
ord-ecd97b47e9694176847c0d32ec8e1dc4
Source dataset
uspto-grants-1976_07
Patent number
US03970459

Reaction notes

Loading…