HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphoric Acid → 1,4,6-Octatriene, 2,7-dimethyl-, (E)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphoric Acid | HCID 1004 | — |
| Reactant | 2,7-Dimethyl-1,3,7-octatriene | HCID 557085 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 1,4,6-Octatriene, 2,7-dimethyl-, (E)- | HCID 528038 | 75.3% |
Reaction Steps
10 g of 2,7-dimethyl-1,3,7-octatriene are kept at reflux temperature under argon atmosphere for 24 hours together with 25 ml of isopropanol and 0.384 g of (PhCN)2PdCl2 and 0,1 g of H3PO4. After this period 75.3% of 2,7-dimethyl-1,4,6-octatriene have been formed (GC-analysis).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03970592 |
| Source dataset | uspto-grants-1976_07 |
| ORD ID | ord-5c6cd08abdec4f56827f9ef5ed5b213e |
| Source note | uspto-grants-1976_07 |