HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tricyclohexylphosphine → 1,4,6-Octatriene, 2,7-dimethyl-, (E)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tricyclohexylphosphine | HCID 75806 | — |
| Reactant | Dimethyl-octa-1,3,7-triene | HCID 54211005 | — |
| Catalyst | Palladium acetylacetonate | HCID 5486778 | — |
| Product | 1,4,6-Octatriene, 2,7-dimethyl-, (E)- | HCID 528038 | 80.3% |
Reaction Steps
10 g of dimethyl-1,3,7-octatriene are kept under argon atmosphere for 36 hours with 0,303 g palladium acetylacetonate, 1,4 g of tricyclohexylphosphine and 0,1 g of H3Po4. After this period, 80.3% of 2,7-dimethyl-1,4,6-octatriene have been formed (GC-analysis).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03970592 |
| Source dataset | uspto-grants-1976_07 |
| ORD ID | ord-a5aa6b04aa4d42d6b2d1bf80c7381fa9 |
| Source note | uspto-grants-1976_07 |