HCID 54333143, compound → HCID 21405852, compound

HRID 918266Notes

Reaction equation

HRID 918266 reaction equation
[C:1]([OH:4])(=[S:3])[CH3:2].[CH3:5][C:6]([CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])=[CH:7][CH:8]=[O:9]>C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[C:1]([S:3][C:6]([CH3:5])([CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH2:7][CH:8]=[O:9])(=[O:4])[CH3:2]

Participants

4

Reactant 2

HCID 54333143HCID 54333143, compoundHCID 178418634HCID 178418634, compound

Product 1

HCID 21405852HCID 21405852, compoundYield 41.3%

Reagents, catalysts & solvents 1

HCID 7187Benzoyl PeroxideCatalyst

Procedure

Freshly distilled thioacetic acid (64 g) was added with stirring and occasional cooling to a mixture of 98 g 3-methyloct-2-enal and 25 mg of benzoyl peroxide. After 5 hours of reflux the mixture was distilled in vacuo through a 20 cm vigreux column yielding 62.5 g (41.3%) of 3-acetylthio-3-methyloctanal, b.p. 100°-112°C/0.5 mm.

Workup

  1. temperatureAfter 5 hours of reflux the mixture
  2. distillationwas distilled in vacuo through a 20 cm vigreux column

Sources & evidence

ORD record
ord-a37c27c965fe4dd697df545b4802a93e
Source dataset
uspto-grants-1976_07
Patent number
US03970689

Reaction notes

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