1-(Chloromethyl)-4-(methanesulfinyl)benzene → 4-Methylthiobenzyltriphenylphosphonium chloride

HRID 918294Notes

Reaction equation

HRID 918294 reaction equation
CS(C1C=CC(C[Cl:9])=CC=1)=O.[Cl-].[CH3:13][S:14]([C:16]1[CH:41]=[CH:40][C:19]([CH2:20][P+:21]([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)=[CH:18][CH:17]=1)=O>>[Cl-:9].[CH3:13][S:14][C:16]1[CH:17]=[CH:18][C:19]([CH2:20][P+:21]([C:22]2[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=2)([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[CH:40][CH:41]=1

Participants

3

Reactant 2

HCID 139696501-(Chloromethyl)-4-(methanesulfinyl)benzeneHCID 21521884{[4-(Methanesulfinyl)phenyl]methyl}(triphenyl)phosphanium chloride

Product 1

HCID 189697944-Methylthiobenzyltriphenylphosphonium chloride

Procedure

In a similar manner, when p-methylsulfinylbenzyl chloride is used, the product is p-methylsulfinylbenzyltriphenylphosphonium chloride, melting point 258°-262°C with gasing.

Sources & evidence

ORD record
ord-40453b2cc8d74902b8ebe4e9a37f2d13
Source dataset
uspto-grants-1976_07
Patent number
US03970693

Reaction notes

Loading…