Ammonia → 3,7,11-Trimethyldodeca-2,4,10-trienylamine

HRID 918331Notes

Reaction equation

HRID 918331 reaction equation
Br[CH2:2][CH:3]=[C:4]([CH3:16])[CH:5]=[CH:6][CH2:7][CH:8]([CH3:15])[CH2:9][CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13].[NH3:17]>C1C=CC=CC=1>[CH3:16][C:4]([CH:5]=[CH:6][CH2:7][CH:8]([CH3:15])[CH2:9][CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13])=[CH:3][CH2:2][NH2:17]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 54370561HCID 54370561, compound

Product 1

HCID 536358993,7,11-Trimethyldodeca-2,4,10-trienylamine

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

Ten grams of 1-bromo-3,7,11-trimethyldodeca-2,4,10-triene is mixed with 50 ml. of benzene, cooled to 5°-10° and saturated with ammonia. The resulting mixture is stirred for 4 hours allowing the temperature to rise to about 20° while maintaining dry conditions. The mixture is washed with dilute sodium hydroxide and then evaporated under reduced pressure to yield 3,7,11-trimethyldodeca-2,4,10-trienylamine.

Workup

  1. customto rise to about 20°
  2. temperaturewhile maintaining
  3. customdry conditions
  4. washThe mixture is washed with dilute sodium hydroxide
  5. customevaporated under reduced pressure

Sources & evidence

ORD record
ord-401a7a630c8d4e2ea5696dc083db04ad
Source dataset
uspto-grants-1976_07
Patent number
US03970704

Reaction notes

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