Methyl 7-methyloct-6-en-2-ynoate → 2,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (2Z)-

HRID 918560Notes

Reaction equation

HRID 918560 reaction equation
[CH3:1][C:2]([CH3:12])=[CH:3][CH2:4][CH2:5][C:6]#[C:7][C:8]([O:10][CH3:11])=[O:9].[CH3:13][Cu]>>[CH3:13]/[C:6](/[CH2:5][CH2:4][CH:3]=[C:2]([CH3:12])[CH3:1])=[CH:7]/[C:8]([O:10][CH3:11])=[O:9]

Participants

3

Reactant 2

HCID 12456227Methyl 7-methyloct-6-en-2-ynoateHCID 178477769HCID 178477769, compound

Product 1

HCID 53659122,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (2Z)-

Procedure

contacting the isolated product of step c with lithium dimethyl cuprate and methyl copper to produce methyl (Z)-3,7-dimethylocta-2,6-dienoate; and

Sources & evidence

ORD record
ord-6fae4d10179b4c3db243258c45cbcbba
Source dataset
uspto-grants-1976_07
Patent number
US03971827

Reaction notes

Loading…