Dimethylamine → HCID 21506104, compound

HRID 918603Notes

Reaction equation

HRID 918603 reaction equation
Cl[C:2]1[C:10]([S:11](=[O:16])(=[O:15])[N:12]([CH3:14])[CH3:13])=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][C:3]=1[N+:17]([O-])=O.C(NS(C1C(Cl)=C([N+]([O-])=O)C=C(C=1)C(O)=O)(=O)=O)CCC.N[C:42]1[CH:43]=[C:44]([CH:48]=[C:49](S(=O)(=O)NC)[C:50]=1[O:51]C1C=CC=CC=1)C(O)=O.CNC.C(N)CCC.NC1CC(S(=O)(=O)NCCCC)(OC2C=CC=CC=2)C=C(C(O)=O)C=1>>[NH2:17][C:3]1[CH:4]=[C:5]([CH:9]=[C:10]([S:11](=[O:16])(=[O:15])[N:12]([CH3:14])[CH3:13])[C:2]=1[O:51][C:50]1[CH:49]=[CH:48][CH:44]=[CH:43][CH:42]=1)[C:6]([OH:8])=[O:7]

Participants

7

Reactant 6

HCID 674DimethylamineHCID 8007ButylamineHCID 215060143-Amino-5-methylsulphamyl-4-phenoxy-benzoic acidHCID 215060165-n-Butylsulphamyl-4-chloro-3-nitro-benzoic acidHCID 215060544-Chloro-5-dimethylsulphamyl-3-nitro-benzoic acidHCID 681407433-Amino-5-n-butylsulphamyl-5-phenoxy-benzoic acid

Product 1

HCID 21506104HCID 21506104, compound

Procedure

The starting materials, 4-chloro-5-dimethylsulphamyl-3-nitro-benzoic acid and 5-n-butylsulphamyl-4-chloro-3-nitro-benzoic acid, were new and were obtained as described for the starting material of Example 2 by substituting aqueous dimethylamine (3.6 g containing 1.5 g of dimethylamine) and n-butylamine (2.2 g), respectively, for the aqueous methylamine, and had melting points of 233°-235°C, and 196°-198°C, respectively.

Workup

  1. customwere obtained
  2. custompoints of 233°-235°C, and 196°-198°C

Sources & evidence

ORD record
ord-f9bb45fbef054bf3aec1c1f78a2ecaf1
Source dataset
uspto-grants-1976_07
Patent number
US03971819

Reaction notes

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