Sulfuric Acid → HCID 65381617, compound

HRID 918648Notes

Reaction equation

HRID 918648 reaction equation
[Cl:1][C:2]1[C:10]([S:11](=[O:14])(=[O:13])[NH2:12])=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][C:3]=1[N+:15]([O-:17])=[O:16].S(=O)(=O)(O)O>C(O)CCC>[CH2:10]([O:7][C:6](=[O:8])[C:5]1[CH:9]=[C:10]([S:11](=[O:13])(=[O:14])[NH2:12])[C:2]([Cl:1])=[C:3]([N+:15]([O-:17])=[O:16])[CH:4]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 1118Sulfuric AcidHCID 898934-Chloro-3-nitro-5-sulphamoylbenzoic acid

Product 1

HCID 65381617HCID 65381617, compound

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

A mixture of 4-chloro-3-nitro-5-sulphamyl-benzoic acid (10 g), n-butanol (100 ml), and conc. sulphuric acid (2 ml) was refluxed for 4 hours, during which 50 ml of the solvent were distilled off slowly. After cooling, the n-butyl-4-chloro-3-nitro-5-sulphamyl-benzoate was isolated by filtration and recrystallized from n-butanol. The compound was obtained with a melting point of 140°-141°C.

Workup

  1. distillationwere distilled off slowly
  2. temperatureAfter cooling

Sources & evidence

ORD record
ord-fdaabcbf2b6b414f9dc03aa233f6c43f
Source dataset
uspto-grants-1976_07
Patent number
US03971819

Reaction notes

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