HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → HCID 57575535, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 5-Bromo-1',2',3',4'-tetrahydro[1,1'-biphenyl]-2-ol | HCID 15190698 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 57575535 | HCID 57575535 | — |
Reaction Steps
A solution of the phenol and MCPBA in benzene is refluxed overnight. A solid is precipitated out and filtered. The filtrate is concentrated under vacuum and chromatographed (10% EtOAc in hexanes) to give 8-bromo-1,2,3,4-tetrahydro-dibenzofuran-4-ol 108 as clear oil, 0.66 g, 39%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09271960B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-9af7dddd9d684f1da263bb500af33723 |
| Source note | uspto-grants-2016_03 |