Sodium ion → 1-(2-Bromopyridin-4-yl)propan-1-one

HRID 92336Notes

Reaction equation

HRID 92336 reaction equation
[Br:1][c:2]1[n:3][cH:4][cH:5][c:6]([CH:8]([CH2:9][CH3:10])[OH:11])[cH:7]1.[CH3:12][C:13]([O:14][I:15]1([O:25][C:26]([CH3:27])=[O:28])([O:29][C:30]([CH3:31])=[O:32])[c:16]2[c:17]([cH:18][cH:19][cH:20][cH:21]2)[C:22](=[O:23])[O:24]1)=[O:33].[Cl:34][CH2:35][Cl:36].[Na+:37].[Na+:38].[O-:39][C:40](=[O:41])[O-:42]>>[Br:1][c:2]1[n:3][cH:4][cH:5][c:6]([C:8]([CH2:9][CH3:10])=[O:11])[cH:7]1

Participants

6

Reactant 5

HCID 923Sodium ion2×HCID 6344DichloromethaneHCID 19660Carbonate IonHCID 159087TriacetoxyperiodinaneHCID 866408041-(2-Bromopyridin-4-yl)-propan-1-ol

Product 1

HCID 592773031-(2-Bromopyridin-4-yl)propan-1-one

Sources & evidence

ORD record
ord-86d79b490e3546509813f6c6d671d404
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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