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HRID925042

反应详情

EQUATION

反应方程式

HRID 925042 的结构方程式

REACTANTS

反应物

3
结构：CC(C)P(Cl)C(C)C
HCID538967

Chlorodiisopropylphosphine

C6H14ClP

结构：[Li]CCCC
HCID178418339

未命名化合物

结构：CC(C)(C)c1ccc(C(=N)Nc2ccccc2C(C)(C)C)cc1
HCID178440935

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)P(N=C(Nc1ccccc1C(C)(C)C)c1ccc(C(C)(C)C)cc1)C(C)C
HCID178460690

未命名化合物

PROCEDURE

实验过程

Procedure as described for NP Amidine I using the following amounts: 1.54 g of 4-tert-butyl-N1-(2-tert-butylphenyl)benzamidine (Amidine VII, 5.0 mmol), 2.50 mL of 2.0 M butyllithium (5.0 mmol), 0.80 mL chlorodiisopropylphosphine (5.0 mmol). After filtration to remove lithium chloride and removal of solvent, a yellow semi-solid was isolated (1.9 g, 100%).

WORKUP

后处理

  1. filtrationAfter filtration
  2. customto remove
  3. customlithium chloride and removal of solvent
  4. customa yellow semi-solid was isolated (1.9 g, 100%)