HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → N'-(2-n-propylphenyl)-N-(diphenylphosphino)-N-methyl-4-methylbenzamidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | N'-(2-n-propylphenyl)-N-(diphenylphosphino)-4-methylbenzamidine | HCID 67297631 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Reactant | HCID 178425630 | HCID 178425630 | — |
| Product | N'-(2-n-propylphenyl)-N-(diphenylphosphino)-N-methyl-4-methylbenzamidine | HCID 67308428 | — |
Reaction Steps
Procedure as described for NSP Amidine III using the following amounts: 1.42 g of N′-(2-n-propylphenyl)-N-(diphenylphosphino)-4-methylbenzamidine (3.0 mmol), 1.50 mL of 2.0 M butyllithium (15.0 mmol), 1.50 mL of 2.0 M methyliodide (3.0 mmol). Following removal of lithium iodide via filtration and removal of solvent in vacuo, a yellow sticky residue was recovered (1.63 g, 67%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09283555B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-88775628eef8434c880cb101af870824 |
| Source note | uspto-grants-2016_03 |