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HRID926108

反应详情

EQUATION

反应方程式

HRID 926108 的结构方程式

REACTANTS

反应物

4
结构：Oc1ccc(S(F)(F)(F)(F)F)cc1
HCID2779203

4-(Pentafluoro-lambda~6~-sulfanyl)phenol

C6H5F5OS

结构：Fc1ccc(S(F)(F)(F)(F)F)cc1
HCID23233210

1-Fluoro-4-(pentafluoro-lambda~6~-sulfanyl)benzene

C6H4F6S

结构：COc1ccc(S(F)(F)(F)(F)F)cc1
HCID59642141

1-Methoxy-4-(pentafluoro-lambda~6~-sulfanyl)benzene

C7H7F5OS

结构：F[B-](F)(F)F.N#[N+]c1ccc(S(F)(F)(F)(F)F)cc1
HCID122235275

未命名化合物

PRODUCTS

生成物

1
结构：COc1ccc(-c2ccc(S(F)(F)(F)(F)F)cc2)cc1
HCID118656365

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

In Methanol: Diazonium salt 1 (22.5 mg, 0.0314 mmol) was dissolved in methanol (0.82 mL). After 13 d stirring at room temp. a portion of the solution was diluted with CDCl3 and analyzed by NMR, which indicated the formation of 1-fluoro-4-(pentafluorosulfanyl)benzene 30, (Umemoto, et al., Beilstein J. Org. Chem. 2012, 8, 461-471) 1-methoxy-4-(pentafluorosulfanyl)-benzene, (Beier, et al., Org. Lett. 2011, 13, 1466-1469) and 4-(pentafluorosulfanyl)phenol (Beier, et al., Org. Lett. 2011, 13, 1466-1469).

WORKUP

后处理

  1. additionwas diluted with CDCl3