HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → HCID 123282959, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | Crotonic Acid | HCID 637090 | — |
| Product | HCID 123282959 | HCID 123282959 | — |
Reaction Steps
Cyclopentene reacted with carbon monoxide (CO) and hydrogen (H2) in the presence of a Wilkinson's catalyst to provide cyclopentanecarboxaldehyde, which then reacted with methylmagnesium chloride (MeMgCl) to provide 1-cyclopentylethanol, which further reacted with crotonic acid in the presence of p-toluenesulfonic acid (pTSA) to afford product but-2-enoic acid 1-cyclopentyl-ethyl ester.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09289366B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-ed878cb012d94833a19abe160e021f55 |
| Source note | uspto-grants-2016_03 |