Potassium Iodide → HCID 87358048, compound

Participants

Reaction Conditions

Reaction Steps

Compound 5 (1.07 g, 2.11 mmol) was dissolved in anhydrous acetonitrile (20 mL) under nitrogen atmosphere. Potassium carbonate (583 mg, 4.22 mmol), potassium iodide (350 mg, 2.11 mmol) and diallylamine (2.6 mL, 21.1 mmol) were added and the reaction mixture heated at 80° C. overnight. After cooling to room temperature, the salts were filtered and the filtrate ware evaporated under reduced pressure. The residue was purified over silica gel using heptane/acetone (9/1) as eluant to give 936 mg (1.79 mmol, 85% yield) of a yellowish oil.

Provenance & Evidence