HuagongsheHuagongshe Chemistry Print Report · For research reference only
Succinic anhydride → HCID 86675382, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Succinic anhydride | HCID 7922 | — |
| Reactant | (3-(1,1,1,3,3,3-hexafluoro-2-(methoxymethoxy)propan-2-yl)-4-(tri butyl-stannyl)phenyl)-N-methylmethanamine | HCID 87358059 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 86675382 | HCID 86675382 | 90% |
Reaction Steps
Compound 14 (114 mg, 184 μmol) was dissolved in freshly distilled THF (3 mL) under nitrogen atmosphere and succinic anhydride (37 mg, 368 μmol) was added. After overnight at 20° C., the solvent was removed under reduced pressure and dissolved in n-hexane. The white precipitate was removed by filtration and the filtrate evaporated to dryness. The residue was purified over silica gel by dichloromethane/methanol (95/5) to give 119 mg (165 μmol, 90% yield) of a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09290421B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-3389b07a4b954228ad8b132779cfe01c |
| Source note | uspto-grants-2016_03 |