HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Hydroxybenzoic Acid → 2,4-Dihydroxybenzoic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Hydroxybenzoic Acid | HCID 135 | — |
| Reactant | Methanol | HCID 887 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Product | 2,4-Dihydroxybenzoic Acid | HCID 1491 | — |
| Product | 2,5-Dihydroxybenzoic acid | HCID 3469 | — |
| Product | 3-Hydroxybenzoic Acid | HCID 7420 | — |
Reaction Steps
Crystallization processes performed with hydroxybenzoic acids gave different results, for example for crystallization of saturated solutions of 4-hydroxybenzoic acid in methanol resulted in a new phase, as shown in FIG. 1. Similarly using methanol or THF, NSF were obtained with the co-formers 3-hydroxybenzoic acid (FIG. 10), 2,4-dihydroxybenzoic acid (FIG. 11), 2,5-dihydroxybenzoic acid (FIGS. 6A, 6B and 6C), 3,4-hydroxybenzoic acid (FIGS. 12A and 12B) and 3,5-hydroxybenzoic acid (FIG. 13).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09290492B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-9dbe10e06db448b8a50a0b69ef73bb04 |
| Source note | uspto-grants-2016_03 |