HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromonaphthalene → 1-Cyclopropylnaphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromonaphthalene | HCID 7001 | — |
| Reactant | HCID 178418630 | HCID 178418630 | — |
| Catalyst | HCID 178418745 | HCID 178418745 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 1-Cyclopropylnaphthalene | HCID 14668693 | — |
Reaction Steps
Cyclopropylmagnesium bromide was added to a solution of bromonaphthalene in tetrahydrofuran stirred at 0-5° C. in the presence of catalytic amount of [1,3-bis(diphenylphosphino)propane]dichloronickel(II) to form cyclopropylnaphthalene, which was diluted with ethyl acetate and washed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09296709B2 |
| Source dataset | uspto-grants-2016_03 |
| ORD ID | ord-fc672e6eabcd45a38a3e24052019a989 |
| Source note | uspto-grants-2016_03 |