Nitric Acid → HCID 86615902, compound

HRID 930174Notes

Reaction equation

HRID 930174 reaction equation
[C:1]1([CH:7]([CH2:13][S:14]([OH:17])(=[O:16])=[O:15])[CH2:8][S:9]([OH:12])(=[O:11])=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.OS(O)(=O)=O.[N+:23]([O-])([OH:25])=[O:24]>>[N+:23]([C:4]1[CH:5]=[CH:6][C:1]([CH:7]([CH2:13][S:14]([OH:17])(=[O:16])=[O:15])[CH2:8][S:9]([OH:12])(=[O:11])=[O:10])=[CH:2][CH:3]=1)([O-:25])=[O:24]

Participants

4

Reactant 3

HCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 86615900HCID 86615900, compound

Product 1

HCID 86615902HCID 86615902, compound

Procedure

2-Phenyl-propane-1,3-disulfonic acid (as prepared in the previous step) is treated with concentrated H2SO4 and fuming HNO3 according to the procedure of Example 2, step (a) to afford the title compound.

Sources & evidence

ORD record
ord-62814f28d5c447b38a673f9ed5ea353d
Source dataset
uspto-grants-2016_03
Patent number
US09296726B2

Reaction notes

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