Sulfuric Acid → Acrylic acid methacrylic acid
Reaction equation
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([OH:11])(=[O:10])[C:7]([CH3:9])=[CH2:8].N(C(C1NCCN=1)(C)C)=NC(C1NCCN=1)(C)C.S(=O)(=O)(O)O>O>[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([OH:11])(=[O:10])[C:7]([CH3:9])=[CH2:8]Participants
6
Reactant 4
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 85 °C
Procedure
Thereafter, a mixture of 10.39 parts by mass of acrylic acid and 111.76 parts by mass of methacrylic acid, and a solution of 14.44 parts by mass of 2,2′-azobis[2-(2-imidazolin-2-yl)propane] and 11.32 parts by mass of concentrated sulfuric acid dissolved in 80.00 parts by mass of deionized water, were simultaneously poured into the flask over 60 minutes. The mixture was kept warm at 85° C. for 2 hours to complete the polymerization reaction, and then the resultant was cooled and taken out. Thus, an acrylic acid/methacrylic acid copolymer was obtained. The non-volatile component fraction was measured, and it was 40% by mass.
Workup
- additionwere simultaneously poured into the flask over 60 minutes
- customthe polymerization reaction
- temperaturethe resultant was cooled
Sources & evidence
- ORD record
- ord-a2d0664037cd42c88f2381d133fb494d
- Source dataset
- uspto-grants-2016_03
- Patent number
- US09299573B2
Reaction notes
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