Potassium Cation → 4-ethynyl-2-fluoro-1-methoxybenzene

HRID 933052Notes

Reaction equation

HRID 933052 reaction equation
[C:12](=[O:13])([O-:14])[O-:15].[CH3:30][OH:31].[F:1][c:2]1[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][c:9]1[O:10][CH3:11].[K+:16].[K+:17].[N+:18](=[C:19]([P:20](=[O:21])([O:22][CH3:23])[O:24][CH3:25])[C:26](=[O:27])[CH3:28])=[N-:29]>>[F:1][c:2]1[cH:3][c:4]([C:5]#[CH:12])[cH:7][cH:8][c:9]1[O:10][CH3:11]

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 676963-Fluoro-p-anisaldehydeHCID 136023029(1E)-1-diazo-1-dimethoxyphosphorylpropan-2-one

Product 1

HCID 64319824-ethynyl-2-fluoro-1-methoxybenzene

Sources & evidence

ORD record
ord-dad0c2df64e144a7811b141a26d0cd79
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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