Dimethyl Sulfoxide → 5-bromo-2-methyl-2H-indazole-4-carbaldehyde

HRID 934361Notes

Reaction equation

HRID 934361 reaction equation
[Br:1][c:2]1[c:3]([CH2:12][OH:13])[c:4]2[cH:5][n:6]([CH3:11])[n:7][c:8]2[cH:9][cH:10]1.[CH3:26][S:27](=[O:28])[CH3:29].[CH3:30][CH2:31][O:32][CH2:33][CH3:34].[I:14]([c:15]1[cH:16][cH:17][cH:18][cH:19][c:20]1[C:21]([OH:22])=[O:23])(=[O:24])=[O:25]>>[Br:1][c:2]1[c:3]([CH:12]=[O:13])[c:4]2[cH:5][n:6]([CH3:11])[n:7][c:8]2[cH:9][cH:10]1

Participants

5

Reactant 4

HCID 679Dimethyl SulfoxideHCID 3283Diethyl EtherHCID 1087942-Iodoxybenzoic acidHCID 59334512(5-bromo-2-methyl-2H-indazol-4-yl)methanol

Product 1

HCID 593346385-bromo-2-methyl-2H-indazole-4-carbaldehyde

Sources & evidence

ORD record
ord-b365bce2aa5e45c8b90e39704e8bfecd
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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