Methanol → 2-Chloro-5-(phenylthio)pyridine

HRID 934848Notes

Reaction equation

HRID 934848 reaction equation
[CH3:16][O-:17].[CH3:19][OH:20].[Cl:1][c:2]1[n:3][cH:4][c:5]([I:8])[cH:6][cH:7]1.[Cu:23].[Na+:18].[Na+:22].[OH-:21].[SH:9][c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1>>[Cl:1][c:2]1[n:3][cH:4][c:5]([S:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[cH:6][cH:7]1

Participants

8

Reactant 7

HCID 887MethanolHCID 923Sodium ion2×HCID 961HydroxideHCID 7969ThiophenolHCID 23978CopperHCID 3826051MethoxideHCID 43971762-Chloro-5-iodopyridine

Product 1

HCID 111953972-Chloro-5-(phenylthio)pyridine

Sources & evidence

ORD record
ord-a1d2d8203c714e69a46eec358b772d70
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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