Potassium Cation → Ethyl 4'-chloro-2'-methyl-biphenyl-2-carboxylate

HRID 936314Notes

Reaction equation

HRID 936314 reaction equation
[Br:1][c:2]1[c:3]([CH3:9])[cH:4][c:5]([Cl:8])[cH:6][cH:7]1.[CH3:10][C:11]1([CH3:12])[C:13]([CH3:14])([CH3:15])[O:16][B:17]([c:18]2[c:19]([C:20](=[O:21])[O:22][CH2:23][CH3:24])[cH:25][cH:26][cH:27][cH:28]2)[O:29]1.[CH3:30][c:31]1[cH:32][cH:33][cH:34][cH:35][cH:36]1.[K+:42].[K+:43].[K+:44].[OH2:45].[P:37]([O-:38])([O-:39])([O-:40])=[O:41]>>[c:2]1(-[c:18]2[c:19]([C:20](=[O:21])[O:22][CH2:23][CH3:24])[cH:25][cH:26][cH:27][cH:28]2)[c:3]([CH3:9])[cH:4][c:5]([Cl:8])[cH:6][cH:7]1

Participants

7

Reactant 6

HCID 813Potassium Cation3×HCID 962WaterHCID 1061PhosphateHCID 1140TolueneHCID 844762-Bromo-5-chlorotolueneHCID 2773962Ethyl 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Product 1

HCID 59492872Ethyl 4'-chloro-2'-methyl-biphenyl-2-carboxylate

Sources & evidence

ORD record
ord-2b8eb54baf9344fbbfe4488f4271310a
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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