Methanol → HCID 45275495, compound

HRID 94000Notes

Reaction equation

HRID 94000 reaction equation
[BH4-:44].[CH3:49][OH:50].[CH3:51][CH:52]([CH3:53])[O-:54].[CH3:56][CH:57]([CH3:58])[O-:59].[CH3:60][CH:61]([CH3:62])[O-:63].[CH3:64][CH:65]([CH3:66])[O-:67].[Cl:46][CH2:47][Cl:48].[NH2:1][CH:2]1[CH2:3][CH2:4][N:5]([C:8]([CH2:9][N:10]2[C:11](=[O:28])[C:12]([c:16]3[cH:17][cH:18][cH:19][cH:20][cH:21]3)([c:22]3[cH:23][cH:24][cH:25][cH:26][cH:27]3)[CH2:13][CH2:14][CH2:15]2)=[O:29])[CH2:6][CH2:7]1.[Na+:45].[O:30]=[C:31]([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)[c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[Ti+4:55]>>[NH:1]([CH:2]1[CH2:3][CH2:4][N:5]([C:8]([CH2:9][N:10]2[C:11](=[O:28])[C:12]([c:16]3[cH:17][cH:18][cH:19][cH:20][cH:21]3)([c:22]3[cH:23][cH:24][cH:25][cH:26][cH:27]3)[CH2:13][CH2:14][CH2:15]2)=[O:29])[CH2:6][CH2:7]1)[CH:31]([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)[c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1

Participants

9

Reactant 8

HCID 887MethanolHCID 923Sodium ionHCID 3102BenzophenoneHCID 6344DichloromethaneHCID 28123BorohydrideHCID 114942Titanium cation (4+)HCID 3260420Isopropanolate4×HCID 673590361-(2-(4-Aminopiperidin-1-yl)-2-oxoethyl)-3,3-diphenylpiperidin-2-one

Product 1

HCID 45275495HCID 45275495, compound

Sources & evidence

ORD record
ord-4565c1b9b0b04641b70aa57d28c5f3de
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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