Sodium ion → 5-Methyl-3-(3-nitro-4-pyridinyl)-2-cyclohexen-1-one

HRID 943729Notes

Reaction equation

HRID 943729 reaction equation
[C:18](=[O:19])([O-:20])[O-:21].[CH3:1][CH:2]1[CH2:3][C:4]([B:9]2[O:10][C:11]([CH3:12])([CH3:13])[C:14]([CH3:15])([CH3:16])[O:17]2)=[CH:5][C:6](=[O:8])[CH2:7]1.[Cl:24][c:25]1[c:26]([N+:31](=[O:32])[O-:33])[cH:27][n:28][cH:29][cH:30]1.[Na+:22].[Na+:23].[O:34]1[CH2:35][CH2:36][O:37][CH2:38][CH2:39]1>>[CH3:1][CH:2]1[CH2:3][C:4]([c:25]2[c:26]([N+:31](=[O:32])[O-:33])[cH:27][n:28][cH:29][cH:30]2)=[CH:5][C:6](=[O:8])[CH2:7]1

Participants

6

Reactant 5

HCID 923Sodium ion2×HCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 27357814-Chloro-3-nitropyridineHCID 592265515-Methyl-2-cyclohexene-1-one-3-boronic acid pinacol ester

Product 1

HCID 592265435-Methyl-3-(3-nitro-4-pyridinyl)-2-cyclohexen-1-one

Sources & evidence

ORD record
ord-562da598cc9d4abaae6eae20690f3d27
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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