Potassium Cation → 2-O-[2-(9-bromo-8-oxo-5,9,10,11-tetrahydronaphtho[2,3-c]isochromen-3-yl)-2-oxoethyl] 1-O-tert-butyl 5-methylpyrrolidine-1,2-dicarboxylate

HRID 944576Notes

Reaction equation

HRID 944576 reaction equation
[Br:1][CH:2]1[C:3](=[O:24])[c:4]2[c:5]([cH:6][c:7]3[c:12]([cH:13]2)[O:11][CH2:10][c:9]2[c:8]-3[cH:17][cH:16][c:15]([C:18]([CH2:19][Br:20])=[O:21])[cH:14]2)[CH2:22][CH2:23]1.[C:25]([CH3:26])([CH3:27])([CH3:28])[O:29][C:30](=[O:31])[N:32]1[CH:33]([C:38](=[O:39])[OH:40])[CH2:34][CH2:35][CH:36]1[CH3:37].[Cl:47][CH2:48][Cl:49].[K+:41].[K+:42].[O-:43][C:44]([O-:45])=[O:46]>>[Br:1][CH:2]1[C:3](=[O:24])[c:4]2[c:5]([cH:6][c:7]3[c:12]([cH:13]2)[O:11][CH2:10][c:9]2[c:8]-3[cH:17][cH:16][c:15]([C:18]([CH2:19][O:40][C:38]([CH:33]3[N:32]([C:30]([O:29][C:25]([CH3:26])([CH3:27])[CH3:28])=[O:31])[CH:36]([CH3:37])[CH2:35][CH2:34]3)=[O:39])=[O:21])[cH:14]2)[CH2:22][CH2:23]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6344DichloromethaneHCID 19660Carbonate IonHCID 235120751-Tert-butoxycarbonyl-5-methyl-pyrrolidine-2-carboxylic acidHCID 866883729-bromo-3-(2-bromoacetyl)-10,11-dihydro-5H-dibenzo[c,g]chromen-8(9H)-one

Product 1

HCID 776907442-O-[2-(9-bromo-8-oxo-5,9,10,11-tetrahydronaphtho[2,3-c]isochromen-3-yl)-2-oxoethyl] 1-O-tert-butyl 5-methylpyrrolidine-1,2-dicarboxylate

Sources & evidence

ORD record
ord-d1cd6a6626f848bd85638eac0af5e288
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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