Dimethyl Sulfoxide → diethyl 2,2,2-trichloroethylidenemalonate

HRID 945239Notes

Reaction equation

HRID 945239 reaction equation
[C:12](=[O:13])([O-:14])[O-:15].[CH3:45][S:46]([CH3:47])=[O:48].[K+:16].[K+:17].[NH2:19][c:20]1[n:21][c:22]2[c:23]([n:24][cH:25][n:26]2[CH:29]2[C:30]([Cl:42])([Cl:43])[C:31]2([C:32](=[O:33])[O:34][CH2:35][CH3:36])[C:37](=[O:38])[O:39][CH2:40][CH3:41])[c:27]([Cl:28])[n:44]1.[NH2:1][c:2]1[n:3][c:4]2[c:5]([nH:6][cH:7][n:8]2)[c:9]([Cl:11])[n:10]1.[OH2:18]>>[Cl:11][C:30]([CH:29]=[C:31]([C:32](=[O:33])[O:34][CH2:35][CH3:36])[C:37](=[O:38])[O:39][CH2:40][CH3:41])([Cl:42])[Cl:43]

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 962WaterHCID 19660Carbonate IonHCID 53603492-Amino-6-chloropurineHCID 9802365HCID 9802365, compound

Product 1

HCID 249806diethyl 2,2,2-trichloroethylidenemalonate

Sources & evidence

ORD record
ord-f8f987660e5b4d8f87f7b1b3f2ed7270
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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