Bromide ion → 1-(3-Chloro-4,5-dipropargyloxyphenyl)butene

HRID 94526Notes

Reaction equation

HRID 94526 reaction equation
[Br-:1].[CH2:24]([Li:25])[CH2:26][CH2:27][CH3:28].[CH2:2]([CH2:3][CH3:4])[P+:5]([c:6]1[cH:7][cH:8][cH:9][cH:10][cH:11]1)([c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1)[c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1.[CH3:46][CH2:47][O:48][CH2:49][CH3:50].[Cl:29][c:30]1[cH:31][c:32]([CH:33]=[O:34])[cH:35][c:36]([O:42][CH2:43][C:44]#[CH:45])[c:37]1[O:38][CH2:39][C:40]#[CH:41]>>[CH:2]([CH2:3][CH3:4])=[CH:33][c:32]1[cH:31][c:30]([Cl:29])[c:37]([O:38][CH2:39][C:40]#[CH:41])[c:36]([O:42][CH2:43][C:44]#[CH:45])[cH:35]1

Participants

6

Reactant 5

HCID 259Bromide ionHCID 3283Diethyl EtherHCID 80375TriphenylpropylphosphoniumHCID 141303053-Chloro-4,5-dipropargyloxybenzaldehydeHCID 178418339Butyllithium

Product 1

HCID 538238081-(3-Chloro-4,5-dipropargyloxyphenyl)butene

Sources & evidence

ORD record
ord-ef801037b2734622850fafe943d579f2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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