Methanol → 4-Methylpyridine-2,3-diamine

HRID 950281Notes

Reaction equation

[CH3:12][OH:13].[NH2:1][c:2]1[n:3][cH:4][cH:5][c:6]([CH3:11])[c:7]1[N+:8]([O-:9])=[O:10].[OH-:14].[OH-:16].[Pd+2:15]>>[NH2:1][c:2]1[n:3][cH:4][cH:5][c:6]([CH3:11])[c:7]1[NH2:8]

Participants

Reactant 4

HCID 887Methanol

HCID 961Hydroxide2×

HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

HCID 2431662-Amino-4-methyl-3-nitropyridine

Product 1

HCID 3174954-Methylpyridine-2,3-diamine

Sources & evidence

ORD record: ord-cc7a8e18065246e2b9c99c30086bcf37
Source dataset: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

Reaction notes

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