Potassium Cation → 2-(tert-Butyl-dimethyl-silanyloxymethyl)-4-ethynyl-tetrahydro-pyran4-ol
Reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[SiH2:5][O:6][C:7]([CH:8]1[O:9][CH2:10][CH2:11][C:12]([OH:14])([C:15]#[C:16][Si:17]([CH3:18])([CH3:19])[CH3:20])[CH2:13]1)([CH3:21])[CH3:22].[K+:23].[K+:24].[O-:25][C:26]([O-:27])=[O:28]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[SiH2:5][O:6][C:7]([CH:8]1[O:9][CH2:10][CH2:11][C:12]([OH:14])([C:15]#[CH:16])[CH2:13]1)([CH3:21])[CH3:22]Participants
4
Sources & evidence
- ORD record
- ord-efa90919ce234dfe8a1dd423983235d8
- Source dataset
- Validation data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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