Sodium ion → 6-Methoxy-2,2-dimethyl-5-nitro-1a,7b-dihydrooxireno[2,3-c]chromene

HRID 951463Notes

Reaction equation

HRID 951463 reaction equation
[CH3:18][n:19]1[cH:20][cH:21][n:22][cH:23]1.[CH3:1][O:2][c:3]1[c:4]([N+:15](=[O:16])[O-:17])[cH:5][c:6]2[c:7]([cH:14]1)[CH:8]=[CH:9][C:10]([CH3:12])([CH3:13])[O:11]2.[CH3:40][C:41]#[N:42].[IH2:24](=[O:25])[c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1.[Mn:39].[Na+:37].[Na+:38].[S:32]([O-:33])([O-:34])(=[O:35])=[S:36]>>[CH3:1][O:2][c:3]1[c:4]([N+:15](=[O:16])[O-:17])[cH:5][c:6]2[c:7]([cH:14]1)[CH:8]1[CH:9]([C:10]([CH3:12])([CH3:13])[O:11]2)[O:25]1

Participants

8

Reactant 7

HCID 923Sodium ion2×HCID 1084Thiosulfate ionHCID 13901-MethylimidazoleHCID 6342AcetonitrileHCID 23930ManganeseHCID 591343256-methoxy-2,2-dimethyl-7-nitro-2H-1-benzopyranHCID 178526216HCID 178526216, compound

Product 1

HCID 575778236-Methoxy-2,2-dimethyl-5-nitro-1a,7b-dihydrooxireno[2,3-c]chromene

Sources & evidence

ORD record
ord-60aa09a6681547599a635410046ee9f4
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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