Potassium Cation → 4-Ethynyl-1-iodo-2-methoxybenzene

HRID 953520Notes

Reaction equation

HRID 953520 reaction equation
[C:12](=[O:13])([O-:14])[O-:15].[CH3:18][O:19][P:20]([C:21](=[N+:22]=[N-:23])[C:24](=[O:25])[CH3:26])(=[O:27])[O:28][CH3:29].[CH3:30][OH:31].[I:1][c:2]1[c:3]([O:10][CH3:11])[cH:4][c:5]([CH:6]=[O:7])[cH:8][cH:9]1.[K+:16].[K+:17]>>[I:1][c:2]1[c:3]([O:10][CH3:11])[cH:4][c:5]([C:6]#[CH:12])[cH:8][cH:9]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 141045564-Iodo-3-methoxybenzaldehydeHCID 136023029(1E)-1-diazo-1-dimethoxyphosphorylpropan-2-one

Product 1

HCID 866614654-Ethynyl-1-iodo-2-methoxybenzene

Sources & evidence

ORD record
ord-1b6b8947e94148ff88103c43d2f43cbd
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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