Acetate → Ethyl 2-(benzyloxy)acetate

HRID 953777Notes

Reaction equation

HRID 953777 reaction equation
[C:20]([O-:21])(=[O:22])[CH3:23].[C:25]([O-:26])(=[O:27])[CH3:28].[Cl:17][CH2:18][Cl:19].[N+:9](=[N-:10])=[CH:11][C:12](=[O:13])[O:14][CH2:15][CH3:16].[OH:1][CH2:2][c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1.[Rh+2:24]>>[O:1]([CH2:2][c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[CH2:11][C:12](=[O:13])[O:14][CH2:15][CH3:16]

Participants

6

Reactant 5

HCID 175Acetate2×HCID 244Benzyl AlcoholHCID 6344DichloromethaneHCID 12192Ethyl diazoacetateHCID 185497Rhodium, ion(Rh2)

Product 1

HCID 290299Ethyl 2-(benzyloxy)acetate

Sources & evidence

ORD record
ord-fa2ba8efccfd48098131b78e260d4933
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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