Potassium Cation → ethyl 4-(2-methyl-7-nitro-1-oxo-2,3-dihydro-1H-isoindol-4-yl)cyclohex-3-ene-1-carboxylate

HRID 955015Notes

Reaction equation

HRID 955015 reaction equation
[C:43](=[O:44])([O-:45])[O-:46].[CH2:52]1[O:53][CH2:54][CH2:55][O:56][CH2:57]1.[CH3:1][N:2]1[C:3](=[O:23])[c:4]2[c:5]([N+:20](=[O:21])[O-:22])[cH:6][cH:7][c:8]([B:11]3[O:12][C:13]([CH3:14])([CH3:15])[C:16]([CH3:17])([CH3:18])[O:19]3)[c:9]2[CH2:10]1.[Cl:49][CH2:50][Cl:51].[F:24][C:25]([F:26])([F:27])[S:28]([O:29][C:30]1=[CH:31][CH2:32][CH:33]([C:36](=[O:37])[O:38][CH2:39][CH3:40])[CH2:34][CH2:35]1)(=[O:41])=[O:42].[K+:47].[K+:48].[OH2:58]>>[CH3:1][N:2]1[C:3](=[O:23])[c:4]2[c:5]([N+:20](=[O:21])[O-:22])[cH:6][cH:7][c:8]([C:30]3=[CH:31][CH2:32][CH:33]([C:36](=[O:37])[O:38][CH2:39][CH3:40])[CH2:34][CH2:35]3)[c:9]2[CH2:10]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 962WaterHCID 6344DichloromethaneHCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 9861195Ethyl 4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-enecarboxylateHCID 672539682-Methyl-7-nitro-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-2,3-dihydro-isoindol-1-one

Product 1

HCID 67253669ethyl 4-(2-methyl-7-nitro-1-oxo-2,3-dihydro-1H-isoindol-4-yl)cyclohex-3-ene-1-carboxylate

Sources & evidence

ORD record
ord-58dfdea337674e4a8e65a024b6da9808
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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