Bicarbonate Ion → 7-Methoxy-1-methyl-1,2,3,4-tetrahydroisoquinoline

HRID 955945Notes

Reaction equation

HRID 955945 reaction equation
[C:18](=[O:19])([OH:20])[O-:21].[C:1]([BH3-:2])#[N:3].[CH3:23][OH:24].[CH3:5][O:6][c:7]1[cH:8][cH:9][c:10]2[c:15]([cH:16]1)[C:14]([CH3:17])=[N:13][CH2:12][CH2:11]2.[Na+:22].[Na+:4]>>[CH3:5][O:6][c:7]1[cH:8][cH:9][c:10]2[c:15]([cH:16]1)[CH:14]([CH3:17])[NH:13][CH2:12][CH2:11]2

Participants

6

Reactant 5

HCID 769Bicarbonate IonHCID 887MethanolHCID 923Sodium ion2×HCID 498716Cyano-borohydrideHCID 150619777-Methoxy-1-methyl-3,4-dihydroisoquinoline

Product 1

HCID 159400117-Methoxy-1-methyl-1,2,3,4-tetrahydroisoquinoline

Sources & evidence

ORD record
ord-fdc2a9e809724275a3c7bc1e9133245e
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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