HRID957026

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID312

Chloride

Cl-

HCID1068

Dimethyl sulfide

C2H6S

HCID3283

Diethyl Ether

C4H10O

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID24593

Copper(1+) bromide

BrCu

结构：O=S(=O)(N(c1ccc(Cl)cn1)S(=O)(=O)C(F)(F)F)C(F)(F)F

HCID388544

N-(5-Chloropyridin-2-yl)-1,1,1-trifluoro-N-(trifluoromethanesulfonyl)methanesulfonamide

C7H3ClF6N2O4S2

HCID22495568

tert-Butyl 4-oxo-3,4-dihydropyridine-1(2H)-carboxylate

C10H15NO3

HCID178477777

未命名化合物

PRODUCTS

生成物

HCID12992764

tert-Butyl 2-methyl-4-oxopiperidine-1-carboxylate

C11H19NO3

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-307a584253e24a34805315d57be53053
来源数据集: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Validation data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][CH2:10][C:11](=[O:14])[CH:12]=[CH:13]1.[CH3:16][Mg+:17].[CH3:18][N:19]([P:20]([N:21]([CH3:22])[CH3:23])([N:24]([CH3:25])[CH3:26])=[O:27])[CH3:28].[CH3:56][CH2:57][O:58][CH2:59][CH3:60].[CH3:61][S:62][CH3:63].[Cl-:15].[Cu:64][Br:65].[F:29][C:30]([F:31])([F:32])[S:33]([N:34]([c:35]1[cH:36][cH:37][c:38]([Cl:39])[cH:40][n:41]1)[S:42]([C:43]([F:44])([F:45])[F:46])(=[O:47])=[O:48])(=[O:49])=[O:50].[O:51]1[CH2:52][CH2:53][CH2:54][CH2:55]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][CH2:10][C:11](=[O:14])[CH2:12][CH:13]1[CH3:18]