Potassium Cation → Diethyl 1-[(2'-t-butoxycarbonylbiphenyl-4-yl)methyl]-2-propylimidazole-4,5-dicarboxylate

HRID 958524Notes

Reaction equation

HRID 958524 reaction equation
[Br:19][CH2:20][c:21]1[cH:22][cH:23][c:24](-[c:27]2[c:28]([C:33](=[O:34])[O:35][C:36]([CH3:37])([CH3:38])[CH3:39])[cH:29][cH:30][cH:31][cH:32]2)[cH:25][cH:26]1.[CH2:1]([CH2:2][CH3:3])[c:4]1[nH:5][c:6]([C:14](=[O:15])[O:16][CH2:17][CH3:18])[c:7]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[n:8]1.[CH3:40][C:41]([CH3:42])([O-:43])[CH3:44].[K+:45]>>[CH2:1]([CH2:2][CH3:3])[c:4]1[n:5][c:6]([C:14](=[O:15])[O:16][CH2:17][CH3:18])[c:7]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[n:8]1[CH2:20][c:21]1[cH:22][cH:23][c:24](-[c:27]2[c:28]([C:33](=[O:34])[O:35][C:36]([CH3:37])([CH3:38])[CH3:39])[cH:29][cH:30][cH:31][cH:32]2)[cH:25][cH:26]1

Participants

5

Reactant 4

HCID 813Potassium CationHCID 45749132-Methylpropan-2-olateHCID 9906257tert-Butyl 4'-(bromomethyl)biphenyl-2-carboxylateHCID 102860151H-Imidazole-4,5-dicarboxylic acid, 2-propyl-, 4,5-diethyl ester

Product 1

HCID 10768304Diethyl 1-[(2'-t-butoxycarbonylbiphenyl-4-yl)methyl]-2-propylimidazole-4,5-dicarboxylate

Sources & evidence

ORD record
ord-84d7bdc67f5e4ab3b4f01b8ca39f2eda
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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