Potassium Cation → 3-(5-Methyl-pyridin-2-yl)-5-nitro-benzoic acid methyl ester

HRID 959804Notes

Reaction equation

HRID 959804 reaction equation
[Br:23][c:24]1[n:25][cH:26][c:27]([CH3:30])[cH:28][cH:29]1.[CH3:1][O:2][C:3]([c:4]1[cH:5][c:6]([N+:19](=[O:20])[O-:21])[cH:7][c:8]([B:10]2[O:11][C:12]([CH3:13])([CH3:14])[C:15]([CH3:16])([CH3:17])[O:18]2)[cH:9]1)=[O:22].[CH3:39][O:40][C:41]([O:42][CH3:43])=[CH2:44].[K+:36].[K+:37].[K+:38].[OH2:45].[P:31]([O-:32])([O-:33])([O-:34])=[O:35]>>[CH3:1][O:2][C:3]([c:4]1[cH:5][c:6]([N+:19](=[O:20])[O-:21])[cH:7][c:8](-[c:24]2[n:25][cH:26][c:27]([CH3:30])[cH:28][cH:29]2)[cH:9]1)=[O:22]

Participants

7

Reactant 6

HCID 813Potassium Cation3×HCID 962WaterHCID 1061PhosphateHCID 136706Ketene dimethyl acetalHCID 5642162-Bromo-5-methylpyridineHCID 44119765Methyl 3-nitro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Product 1

HCID 578516583-(5-Methyl-pyridin-2-yl)-5-nitro-benzoic acid methyl ester

Sources & evidence

ORD record
ord-a98b2040857a4e6792f2dbd83c4a93fa
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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