Ethanol → 1-(6-Chloro-3-pyridylmethyl)-2-(1-nitro-2-trimethylsilylmethylthioethylidene)imidazolidine

HRID 960659Notes

Reaction equation

HRID 960659 reaction equation
[CH2:18]=[O:19].[CH3:26][CH2:27][OH:28].[Cl:1][c:2]1[cH:3][cH:4][c:5]([CH2:8][N:9]2[C:10](=[CH:14][N+:15](=[O:16])[O-:17])[NH:11][CH2:12][CH2:13]2)[cH:6][n:7]1.[SH:20][CH2:21][Si:22]([CH3:23])([CH3:24])[CH3:25]>>[Cl:1][c:2]1[cH:3][cH:4][c:5]([CH2:8][N:9]2[C:10](=[C:14]([N+:15](=[O:16])[O-:17])[CH2:18][S:20][CH2:21][Si:22]([CH3:23])([CH3:24])[CH3:25])[NH:11][CH2:12][CH2:13]2)[cH:6][n:7]1

Participants

5

Reactant 4

HCID 702EthanolHCID 712FormaldehydeHCID 140342Methanethiol, trimethylsilyl-HCID 1809572-Chloro-5-{[2-(nitromethylidene)imidazolidin-1-yl]methyl}pyridine

Product 1

HCID 867473281-(6-Chloro-3-pyridylmethyl)-2-(1-nitro-2-trimethylsilylmethylthioethylidene)imidazolidine

Sources & evidence

ORD record
ord-48a7c3e62b3244f5bb4b3f20fa25490d
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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