Sodium ion → 6-Bromo-1-methyl-1,2,3,4-tetrahydroisoquinoline

HRID 961165Notes

Reaction equation

[Br:1][c:2]1[cH:3][c:4]2[c:9]([cH:10][cH:11]1)[C:8]([CH3:12])=[N:7][CH2:6][CH2:5]2.[C:13]([O:14][BH-:15]([O:16][C:17](=[O:18])[CH3:19])[O:20][C:21](=[O:22])[CH3:23])(=[O:24])[CH3:25].[Na+:26]>>[Br:1][c:2]1[cH:3][c:4]2[c:9]([cH:10][cH:11]1)[CH:8]([CH3:12])[NH:7][CH2:6][CH2:5]2

Participants

Reactant 3

HCID 923Sodium ion

HCID 2724942Triacetoxyborohydride

HCID 584163806-Bromo-1-methyl-3,4-dihydroisoquinoline

Product 1

HCID 596625906-Bromo-1-methyl-1,2,3,4-tetrahydroisoquinoline

Sources & evidence

ORD record: ord-fb7d0592c765489eae611f1904a41054
Source dataset: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

Reaction notes

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