Dichloromethane → (4-Benzylsulfanyl-5-nitro-thiophen-3-yl)-methanol

HRID 962078Notes

Reaction equation

HRID 962078 reaction equation
[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[S:8][c:9]1[c:10]([C:17](=[O:18])[O:19][CH3:20])[cH:11][s:12][c:13]1[N+:14](=[O:15])[O-:16].[CH2:22]([Al+:23][CH2:24][CH:25]([CH3:26])[CH3:27])[CH:28]([CH3:29])[CH3:30].[Cl:31][CH2:32][Cl:33].[H-:21]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[S:8][c:9]1[c:10]([CH2:17][OH:18])[cH:11][s:12][c:13]1[N+:14](=[O:15])[O-:16]

Participants

5

Reactant 4

HCID 6344DichloromethaneHCID 166653HydrideHCID 851124Methyl 4-benzylsulfanyl-5-nitrothiophene-3-carboxylateHCID 16686348Bis(2-methylpropyl)alumanylium

Product 1

HCID 59168797(4-Benzylsulfanyl-5-nitro-thiophen-3-yl)-methanol

Sources & evidence

ORD record
ord-26ca785517934bcabf772f1bd481777c
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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