HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-(4-Nitrobenzoyl)-6 7-dihydro-5H-dibenz[b,d]azepine → 5-(4-Aminobenzoyl)-6,7-dihydro-5H-dibenz[b,d]azepine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-(4-Nitrobenzoyl)-6 7-dihydro-5H-dibenz[b,d]azepine | HCID 54006554 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol ethylacetate | HCID 21584252 | — |
| Product | 5-(4-Aminobenzoyl)-6,7-dihydro-5H-dibenz[b,d]azepine | HCID 53844495 | 94.9% |
Reaction Steps
A solution of 0.15 g of 5-(4-nitrobenzoyl)-6,7-dihydro-5H-dibenz[b,d]azepine in 20 μl of ethanol-ethyl acetate and 10 mg of 10% palladium-on-carbon is hydrogenated under 35 pounds per square inch of hydrogen for 8 hr. The mixture is filtered through diatomaceous earth and the filtrate evaporated to give 0.13 g of product as a light yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05760031 |
| Source dataset | uspto-grants-1998_06 |
| ORD ID | ord-53d23ec73678481e9e4ffd82e1b64a14 |
| Source note | uspto-grants-1998_06 |